8-Hydroxy-2-methylquinolinium diiodido(2-methylquinolin-8-olato-κ2 N,O)zincate(II) methanol monosolvate
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چکیده
The anion of the title salt, (C(10)H(10)NO)[Zn(C(10)H(8)NO)I(2)]·CH(3)OH, has its metal atom N,O-chelated by the deprotonated 2-methyl-8-hy-droxy-quinoline ligand. The hy-droxy unit of the cation is a hydrogen-bond donor to the alkoxide O atom of the tetra-hedrally coordinated anion, whereas the ammonium cation acts as a hydrogen-bond donor to the methano-lic O atom. In the crystal, adjacent ion pairs and solvent mol-ecules are linked by a methanol-halogen O-H⋯I hydrogen bond, generating a chain running along the a axis.
منابع مشابه
8-Hydroxy-2-methylquinolinium dibromido(2-methylquinolin-8-olato-κ2 N,O)zincate(II) methanol monosolvate
The anion of the title salt, (C(10)H(10)NO)[ZnBr(2)(C(10)H(8)NO)]·CH(3)OH, has its metal atom N,O-chelated by the deprotonated 2-methyl-8-hy-droxy-quinoline ligand. The hy-droxy unit of the cation is a hydrogen-bond donor to the alkoxide O atom of the tetra-hedrally coordinated anion, whereas the ammonium cation is a hydrogen-bond donor to the methano-lic O atom. In the crystal, adjacent ion pa...
متن کامل8-Hydroxy-2-methylquinolinium diiodido(2-methylquinolin-8-olato-κ2 N,O)zincate
The reaction of 2-methyl-8-hy-droxy-quinoline and zinc iodide in acetonitrile affords the title salt, (C(10)H(10)NO)[Zn(C(10)H(8)NO)I(2)], in which the Zn(II) ion is coordinated by a N,O-chelating 2-methyl-quinolin-8-olate ligand and two iodide ligands in a distorted tetra-hedral geometry. The cation is linked to the anion by an O-H⋯O hydrogen bond.
متن کامل8-Hydroxy-2-methylquinolinium dibromido(2-methylquinolin-8-olato-κ2 N,O)zincate acetonitrile monosolvate
The reaction of 2-methyl-8-hy-droxy-quinoline and zinc bromide in acetonitrile affords the title solvated salt, (C(10)H(10)NO)[ZnBr(2)(C(10)H(8)NO)]·CH(3)CN, in which the Zn(II) ion is coordinated by a N,O-chelating 2-methyl-quinolin-8-olate ligand and two bromide ligands in a distorted tetra-hedral geometry. The cation is linked to the anion by an O-H⋯O hydrogen bond and the quinolinium H atom...
متن کامل8-Hydroxy-2-methylquinolinium dichlorido(2-methylquinolin-8-olato-κ2 N,O)zincate acetonitrile disolvate
The reaction of 2-methyl-8-hy-droxy-quinoline and zinc chloride in acetonitrile affords the title solvated salt, (C(10)H(10)NO)[Zn(C(10)H(8)NO)Cl(2)]·2CH(3)CN, in which the Zn(II) atom is coordinated by an- N,O-chelating 2-methyl-quinolin-8-olate ligand and two chloride ligands in a distorted tetra-hedral geometry. The cation is linked to the heterocyclic anion by an O-H⋯O hydrogen bond and the...
متن کامل8-Hydroxy-2-methylquinolinium dichlorido(2-methylquinolin-8-olato-κ2 N,O)zincate(II) methanol solvate
The reaction of zinc chloride and 2-methyl-8-hydroxy-quinoline in methanol yielded the title monosolvated salt, (C(10)H(10)NO)[ZnCl(2)(C(10)H(8)NO)]·CH(3)OH, which has the Zn atom within a distorted Cl(2)NO tetra-hedral coordination geometry. Supra-molecular chains feature in the crystal structure, comprising all components of the structure stabilized by a combination of O-H⋯O, N-H⋯O and O-H⋯Cl...
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